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We currently provide SSO to our users only while they are enrolled. Once they graduate, we remove them from AD and they have to login direct with their Live credentials.
Can this be accomplished in Office365?
Unfortunately no unless you changed their login ID to a non federated name which I am assuming isn't feasable. Even then you'd have to convert their account to a non-dirsync account which woudl be tricky. You'd probably have to create a cloud only account then export the mail from the AD account and import it into the new account. Otherwise you'd have to keep the account active for them to continue logging in to the O365 account offered by the school.
Jorge R. Diaz
Microsoft MVP | Office 365
MCITP: Office 365 Administrator
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Hi B Anderson,
How are things going on your side? If you need further assistance on this issue, please feel free to contact us.